Roasters on a map
What makes a roaster specialty?
The goal of specialty roasting is to preserve the natural character and origin of the coffee bean. The master roaster creates a unique profile for each batch to preserve and highlight the aromas derived from the processing of the coffee cherry and the characteristics of the terroir.
Precise origin and traceability
Unlike industrial production, the journey of the coffee bean can often be traced back to the specific farm.
Respect for processing
The roasting process takes into account what happened to the coffee cherry after harvesting. Whether it is washed, natural, or anaerobically fermented determines the roasting method, which aims to create a balance of fruitiness and sweetness.
Variety and genetics
Each coffee variety (e.g., Bourbon, Geisha) has its own flavor profile. The goal of a specialty roaster is not to "burn away" the characteristic notes of the variety, but to let them shine.
Roasting levels
As the temperature rises during roasting, the natural flavor of the coffee bean gives way to the aromas of the roast:
- Light roast: The coffee's flavor is dominated by its origin and variety.
- Medium roast: The original flavors are accompanied by sweet, chocolatey tones.
- Dark roast: The heat suppresses the uniqueness of the coffee bean, and the taste becomes bitter and universal.
Processing Methods
Processing methods were not created by chance; their development was driven by necessity, environmental conditions, and the desire to maximize flavors.
Natural (Dry)
This method originated in places with water scarcity (e.g., parts of Ethiopia, Brazil). The coffee was simply spread out in the sun to dry with the fruit pulp intact.
Washed
This developed where water was plentiful, but humidity was too high for slow drying. Here, water was used to quickly remove the fruit pulp to prevent rotting.
Honey
Originating from Costa Rica in the 2000s, the goal was to combine the cleanliness of washed coffees with the sweetness of natural coffees while saving water.
Anaerobic Fermentation
The coffee beans (with or without pulp) are placed in stainless steel tanks and sealed hermetically. Lactic acid bacteria become dominant. Under high pressure, the sugars and aromatic compounds (esters) in the pulp (mucilage) are "pressed" into the coffee bean (the seed) instead of escaping.
Carbonic Maceration
This technique was directly adopted from winemaking. The coffee is not just sealed in a tank; carbon dioxide (CO₂) is actively pumped in, displacing all oxygen. The coffee beans are placed inside as whole cherries (with the skin on).
Giling Basah (Wet Hulled)
While in most parts of the world the hard protective layer (endocarp) is removed only at the very end of drying, the Indonesian Giling Basah method breaks this rule. In tropical Indonesia, the extreme humidity would cause the coffee to rot inside the sealed parchment, so farmers mechanically break the hull at 30-35% moisture content. This creates the deep color and unique heavy, earthy-spicy aromas characteristic of Indonesian coffees.
Coffee Roasting
According to its food industry definition, coffee roasting is a reactive drying process accompanied by simultaneous heat and mass transfer. The input material of the process, green coffee, is a chemically stable endosperm.
Although we call it a "coffee bean," it actually has nothing to do with beans or legumes. Imagine a red fruit that looks exactly like a cherry. When this fruit is "pitted," the seed inside is what we call the coffee bean.
The endosperm is essentially the plant's "packed lunch." It is full of nutrients (sugars, acids, proteins) that are there so that if the seed is planted, it has the energy to grow out of the ground.
How does this become a characteristic coffee bean?
When this seed is roasted, these stored nutrients get "cooked." They transform under the influence of heat, and that is when the scents and aromas we know as coffee flavor are created. These nutrients are mostly non-volatile in green coffee, so they are barely or not at all perceptible by smell. The volatile compounds necessary for the characteristic aroma sensation of coffee only appear during roasting, under the influence of heat.
During the roasting process, the coffee bean undergoes significant physical and chemical changes: its mass decreases, its volume increases, while a large number of new volatile and non-volatile compounds are created. These volatile components play a crucial role in forming the coffee's aroma profile, as they are directly responsible for the sensation of smell and taste.
The formation of volatile aroma compounds is primarily the result of heat-driven reactions in which sugars and amino acids interact with each other or with their decomposition products. These reactions form the chemical basis of aroma formation during roasting; to understand this in detail, knowledge of the browning and decomposition processes discussed later is essential.
Flavor Potential
Flavor potential is determined by the presence of macro- and micronutrients. If these are absent, there is no point in roasting. We call these precursors.
- Carbohydrates (50%): Polysaccharides forming the bean's skeleton (cellulose, hemicellulose, arabinogalactans) are responsible for structural integrity. Free sugars (mainly sucrose: 6-9% in Arabica, 3-7% in Robusta) are the primary sources of acidity and sweetness.
- Lipids (12-18%): Triglycerides and diterpenes (cafestol, kahweol). Lipids carry the aromas and are responsible for the creaminess of the "mouthfeel." They are chemically stable during roasting, but their physical position changes (migration).
- Nitrogen-containing compounds (11-15%): Proteins, free amino acids, and alkaloids (caffeine, trigonelline). Free amino acids are essential reactants for the Maillard reaction.
- Chlorogenic Acids (CGA): Green coffee is one of the plant kingdom's richest sources of CGA (mainly 5-caffeoylquinic acid). These phenolic compounds are precursors to bitterness, astringency, and acidity.
- Water (10-12%): Not merely a solvent, but a moderator of chemical reactions and a medium for heat transfer.
Heat Regulation
For flavors to develop from precursors, proper heat regulation is required so that the entire roasting process yields the desired flavor result.
In the first half of roasting (from room temperature to approx. 170-180°C), the coffee bean behaves in an endothermic manner, absorbing heat. When the bean temperature reaches approx. 190-200°C (around first crack), the situation changes dramatically. The process becomes exothermic. From the Greek word exo (external). What does this mean? Chemical reactions occurring inside the bean (mainly the decomposition of organic matter, cellulose cracking, and pyrolysis) suddenly begin to generate heat. The coffee bean no longer just "asks" for energy, but "gives" it too. Because the processes occurring within the coffee bean generate heat energy themselves.
The coffee bean interacts with heat in several ways; knowledge of these is necessary because, as we will see at the end of the monograph, poor control of these contributes to bad taste sensations.
Heat Transfer Mechanisms
- Conduction: Direct contact of the bean with the hot drum wall. This dominates the beginning of the process in traditional drum roasters. Excessive conduction can cause surface scorching.
- Convection: The flow of hot air between the beans. This is the most efficient way to get energy into the bean's core. Modern fluid-bed roasters use this almost 100%. Convection improves acidity preservation.
- Radiation: Thermal radiation between hot metal surfaces and the beans themselves.
PHASES OF CHEMICAL TRANSFORMATION
Roasting can be conceived as a chemical reactor where different reaction windows open as the temperature rises.
Dehydration and "Glass Transition" (Room Temp. – 130°C)
The first stage of the process is the removal of free and bound water. The structure of the beans transitions from a "glassy" state to a "rubbery" state (Glass Transition Temperature). This phase transition allows for the bean's volume expansion. Chemical reactions are minimal here; the breakdown of chlorophyll causes yellowing. As the temperature increases, we reach the Maillard reaction.
The Maillard Reaction: The Engine of Aromagenesis (130°C – 160°C)
This is the most critical stage, a series of non-enzymatic browning reactions.
The reaction was named after Louis-Camille Maillard. He was a French physician and chemist, and the story began in 1912. The funniest part is that Maillard wasn't interested in coffee or gastronomy at all. He was interested in human cells. He was researching how proteins are built in our cells. While experimenting, he heated sugars and amino acids (the building blocks of proteins) together in test tubes, hoping to discover the secret of life.
Instead, what happened? The mixture in the test tube didn't assemble into protein but turned brown and began emitting entirely new, characteristic scents. Maillard described the phenomenon, shrugged saying "well, that's an interesting chemical process," published his study, and went about his business.
The History: The Army's "Inedible" Food
His discovery gathered dust in a drawer for decades. Scientists knew about it but didn't attach much importance to it. Then came World War II, and the Maillard reaction suddenly became important (or at least a moral issue). The US Army sent tons of preserved food (powdered eggs, powdered milk, powdered potatoes) to the front.
The problem was that these powders turned brown on their own during storage and became disgusting in taste, even though they hadn't been cooked. The soldiers hated them. The army scientists started scratching their heads: "Why does the egg powder turn brown in the bag?" That's when they pulled out Maillard's old study. They realized that the same reaction was taking place, just slowly, at low temperatures, and this was ruining the food.
- The Lesson: The Maillard reaction, when controlled (during frying, roasting), yields the world's most delicious flavors. Uncontrolled (during storage), however, it ruins food.
- Maillard Reaction: Under the influence of heat, sugars and amino acids (proteins) chemically link together. Since this initial connection is very unstable, the structure of the resulting molecule quickly rearranges – this chemical "positioning" triggers browning and the birth of flavors. Scientifically speaking: The carbonyl group of reducing sugars and the amino group of free amino acids condense, creating N-substituted glycosylamine. This is unstable and undergoes Amadori rearrangement.
- Degradation: The pH-dependent decomposition of Amadori products creates heterocyclic compounds:
- Pyrazines: Earthy, nutty, roasted aromas.
- Pyrroles: Cereal notes.
- Thiophenes: Meaty, roasted scents derived from sulfur-containing amino acids.
- Melanoidins: The end products of the reaction are brown-colored polymers that possess antioxidant effects and increase the body of the coffee.
These reactions trigger Strecker degradation at a certain point; they appear almost simultaneously.
Strecker Degradation (140°C – 170°C)
By-products of the Maillard reaction (α-dicarbonyls) react with amino acids, inducing decarboxylation (CO2 release).
- Significance: This reaction creates coffee-specific aldehydes.
- Leucine → 3-methyl-butanal (Malty/Chocolatey).
- Phenylalanine → Phenylacetaldehyde (Honey/Floral).
- Methionine → Methional (Boiled potato/Earthy).
- These compounds evaporate in the first phase of roasting. This explains why floral-fruity notes dominate in light roasts.
The reaction was named after German chemist Adolph Strecker. And here comes the twist: Strecker described this process in 1862 – exactly 50 years before Maillard discovered his own reaction!
- The Situation: Strecker was a typical, precise German scientist of the mid-19th century. He experimented with organic chemistry at the University of Tübingen.
- The Experiment: He wasn't roasting coffee. He was examining the reaction between a compound called alloxan (a derivative of uric acid) and various amino acids. He noticed that if he poured these two together, something strange happened: the amino acid fell apart, and compounds with characteristic smells were created.
Why "Degradation"?
The name sounds a bit scary ("degrading" = lowering in quality, deteriorating), but in a chemical sense, it simply means: falling apart into a simpler form. Strecker realized that in this reaction, the amino acid loses a carbon atom (leaving as carbon dioxide), so the molecule "becomes smaller," it degrades.
- The amino acid becomes an Aldehyde.
- And this is the essence: Aldehydes are the world's most fragrant compounds. This is why almonds smell like almond, vanilla like vanilla, and coffee has honey/floral aromas.
In roasting, Strecker degradation is a kind of "secondary" process that rides on the back of the Maillard reaction.
- The Prequel: The Maillard reaction (the big guy) produces a bunch of by-products (dicarbonyls).
- The Strecker Moment: These by-products meet the remaining amino acids and "tear them apart."
- Strecker: "Hey, amino acid, give me your carbon dioxide!"
- Result: Boom, a cloud of fragrance (aldehyde) is created.
The Finale: Sugar Degradation, Caramel, and Acids (160°C – 200°C)
How does sweet become bitter, and fruity become winey? As the temperature crosses 160°C, the Maillard reaction begins to slow down (free amino acids run out), and pure sugar chemistry takes over. Here, sugar no longer reacts with protein, but with itself and heat.
This stage involves two intertwined processes:
A) Caramelization (The Transformation of Sweetness)
The sucrose in green coffee (6-9%) begins to decompose drastically.
- Hydrolysis: Sucrose breaks down into glucose and fructose.
- Dehydration: They lose water and turn into anhydrides.
- Flavors:
- Furans and maltol form (this is the classic caramel, toasted sugar scent).
- As roasting progresses, sweetness decreases, and the bitter, "roasted" character appears.
B) Acidity Modulation (The Most Complex Part)
This is where the biggest change in coffee character happens. The acid profile doesn't simply "decrease," it gets exchanged.
- Decomposition of "Good" Acids (Thermolabile acids):
- Heat-sensitive acids that provide fresh fruitiness, such as citric acid and malic acid, begin to break down.
- Effect: The citrusy vibrancy of light roasts disappears.
- Birth of New Acids:
- During the breakdown of sugars (sucrose), not only caramel flavors but also aliphatic carboxylic acids are created.
- Such as acetic acid and formic acid.
- Effect: These acids give the coffee a heavier, more complex, sometimes fermented, winey, or syrupy character.
When Chemistry Becomes Physics – Pressure
But alongside chemistry, physics is also at work. The decomposition of sugars involves pressure. The hard structure of the coffee bean holds this increasing internal pressure for a while, but a point comes when the material gives in.
Why does it involve pressure?
- Water (Steam formation): Raw green coffee isn't entirely dry; it contains approx. 10-12% water. When the temperature crosses 100°C, this water begins to turn into steam.
- Physics: Water steam needs approx. 1600 times more space than liquid water. Since the bean size cannot grow that fast, the steam begins to strain the walls.
- Chemistry (Gas production): The previously discussed reactions (Maillard, Strecker, sugar breakdown) create not only colors and flavors but also plenty of gas as a by-product, mainly carbon dioxide (CO₂) and carbon monoxide.
Explosion - Crack
Coffee bean cell walls are made of thick cellulose (like wood). This material is very hard and dense, not allowing the generated steam and gases to escape. Therefore, internal pressure increases until the cellulose wall reaches its load-bearing limit (approx. 20-25 bar). This is when the explosion (crack) happens. This is the first crack; during the second, the charring of organic matter (carbonization) begins. A new wave of carbon dioxide formation cracks the bean. At approx. 224°C. Lipid migration: Due to cell destruction, oils are pressed to the surface through capillaries ("sweating" coffee bean). Flavor state: "Dark Roast". Acids are gone, sugars are burnt. Bitter, smoky, heavy profile.
THE CHEMISTRY OF BITTERNESS: THE CHLOROGENIC ACID CASCADE
While the bean physically cracks and pops, the character of bitterness also undergoes a dramatic transformation. Bitterness is not static but changes with temperature, in two main phases:
- Lactonization (Medium Roast): Chlorogenic acids (CGA) turn into chlorogenic acid lactones via dehydration.
- Sensory Effect: Clean, pleasant, "quality" bitterness (similar to quinine or grapefruit).
- Oligomerization (Dark Roast): Lactones further decompose and polymerize into phenylindanes.
- Sensory Effect: Metallic, harsh, astringent bitterness that lingers on the tongue. A characteristic of very dark roast coffees (e.g., Neapolitan style).
Final Flavor Profile
The coffee's final flavor profile is not the work of a single moment but the combined result of all the chemical processes discussed so far. The character is determined not only by how high a temperature we reached but also by how much time it took to get there. We call this the "Time-Temperature Integral": the end result is the joint imprint of heat and time.
The Role of Development Time (DT)
This time window lasts from the moment of the first crack until the beans are dumped. In this phase, the roast master fine-tunes the end result not with force (heat) but with timing.
- Short DT (Underdevelopment): Like a half-baked cake; the process is interrupted too soon, so chemical reactions get stuck in an early stage. Since sugar polymerization didn't complete, melanoidins giving creaminess are missing, so the drink's texture is thin and watery. The result is a disharmonious profile: acidity is sharp and offensively sour, often accompanied by raw, "vegetal" notes (grass, green peas), which is an unmistakable sign of unfinished Strecker degradation.
- Optimal DT (Approx. 20-25% of total time): This is the golden mean, the ideal range according to professional consensus. Perfect synergy is created here: acid edges have rounded off – they don't scratch – but fruitiness is still vibrant. Caramelization of sugars (sweetness) and formation of melanoidins (body) reach a maximum, creating a harmonious balance of acidity and creamy texture.
- Long DT (Overdevelopment): If this phase is dragged out, the coffee gets "overcooked." Heat-sensitive organic acids and volatile, fruity aldehydes decompose or evaporate. The profile goes "flat": excitement and character disappear, replaced by dominant pyrazines (pure roasted taste). The end result is a boring, "baked" flavor world reminiscent of toast crust.
Roast Degrees: What Does the Color Reveal?
While the most conspicuous result of roasting is the browning of the beans, the human eye is often a deceptive instrument. Ambient lighting conditions or fatigue can easily mislead a roaster; therefore, modern industry utilizes the objective Agtron scale instead of subjective "eyeballing."
The Physics of Measurement: Why NIR?
Measuring instruments do not actually see "color" in the human sense; instead, they monitor the Near-Infrared (NIR) spectrum. Every substance possesses a unique "optical fingerprint." The measurement is based on the differing light reflectance of materials:
- Light Absorption: As sugars caramelize and cellulose carbonizes, the material's ability to reflect light changes. The darker (more advanced) the roast, the more infrared light is absorbed by the resulting carbon chains, and the less light the sample reflects.
In instrumental measurement, the rule is simple: a decrease in infrared reflectance indicates a higher presence of carbon—meaning the coffee is more highly roasted.
The Trap: When Numbers Lie
In the foregoing, we revealed how science – from Herschel's prism to Carl Staub's instrument – enabled us to objectively measure the chemical "maturity" of the coffee bean using infrared light. The Agtron scale shows exactly where we have arrived on the sugar-carbon axis.
However, roasting is not just about reaching the destination, but also about the journey there. Even behind a seemingly perfect Agtron average value (e.g., 55), defects can hide which the machine might not see, but the tongue immediately detects.
Scorching (Surface Charring)
This defect typically occurs at the very beginning of roasting, in the Charge phase.
- The Physical Cause (Conduction Shock): The temperature of the roasting drum's metal wall is too high compared to the heat absorption capacity of the beans. The flat side of the beans touches the hot metal. Since cellulose is a poor heat conductor, heat cannot flow into the bean's interior fast enough, so it piles up on the surface.
- The Chemical Background: Local, premature pyrolysis (thermal decomposition) takes place on the bean surface.
- Surface sugars and fibers immediately char (carbonize), skipping the delicate phases of the Maillard reaction and caramelization.
- While the surface is already "Agtron 20" (charred), the inside of the bean is still raw.
Tipping (Tip Burning – A Geometrical Defect)
Although similar to Scorching, Tipping usually develops in the later stage of roasting, or due to overly aggressive air circulation (convection).
- The Physical Cause (Geometrical Overheating): The coffee bean is not spherical. Its ends (where the embryo is located) are thinner and have less mass than the center. If heat transfer is too intense, these thin points heat up much faster than the rest of the bean ("heat shock").
- The Chemical Background: Local drying out and burning. Water evaporates from the end of the bean in moments, so the cooling effect of evaporation ceases. The unprotected organic matter burns immediately.
Baking
This is one of the most insidious defects for roasters because visually it is hard to notice (the bean might look nicely brown), but the flavor is lost. It usually occurs around or after the first crack.
- The Physical Cause (RoR Crash): The "Rate of Rise" (the speed of temperature increase) slows down drastically, drops to zero, or turns negative (the bean starts cooling). The roasting loses its "momentum."
- The Chemical Background (Stalled Reactions):
- Maillard Reaction: An endothermic (heat-absorbing) process that requires continuous energy supply. If heat supply ceases, the reaction "suffocates." Instead of complex, volatile aroma molecules (aldehydes, ketones), stable, tasteless polymers are formed (cross-links are created between proteins and sugars).
- Caramelization: Does not kick in properly because the necessary temperature dynamics are missing. Sugars don't break down into exciting flavor substances, they just "dry out."
- Acids: Organic acids (e.g., citric acid) break down but do not transform into sweeter derivatives.
- Visual Sign: The bean surface is matte, lackluster (dull), lacking oily sheen, as internal pressure was not high enough to press oils to the surface.
Quakers (Immature Beans – A Raw Material Defect)
This is the only defect for which the roast master is not responsible, but the producer (or lack of sorting) is.
- The Physical Cause (Low Density): Beans from immature cherries have much lower density, their structure is undeveloped.
- The Chemical Background (Lack of "Fuel"):
- For roasting browning (Maillard reaction, caramelization), reducing sugars and amino acids are needed.
- In immature beans, these precursors are missing. There is no "fuel" to turn brown.
- Therefore, during roasting, these beans behave in a chemically inert way: they only lose water but do not transform.
- Visual Sign: Light, yellowish-orange, peanut-colored beans remain among the dark brown beans (even in dark roasts).
- Sensory Profile: Since chlorogenic acids did not break down, and sugar was not formed to mask them, the taste is astringent. Distinctive tastes are peanut, popcorn hull, paper, and dry wood. A single Quaker can ruin the taste of an entire cup of coffee.